432 research outputs found

    Evaluation of the present theoretical basis for determination of planetary surface properties by earth-based radar

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    Spaceflight programs such as the planned Viking landing on Mars require the determination of planetary surface slopes and surface dielectric constants by earth-based methods. Heavy reliance is often placed on radar backscattering data for estimation of these surface properties. An assessment is presented of the basic theory by which the raw radar data are interpreted, and it is shown that serious difficulties and internal inconsistencies are present in the available theoretical formulas. The discussion brings into question the reliability of the presently available results for these surface properties as obtained by earth-based radar methods

    Electronic compensation for reflector surface distortion to improve radiation pattern characteristics of antennas

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    A simple procedure is described for determining the excitation coefficients of an array feed which compensates for the surface distortion of a reflector antenna to improve the radiation pattern in such a way as to approximate the performance of the undistorted antenna. A computer simulation for a practical feed array is presented as an example of compensation for the distortion of an actual antenna

    DIAL with heterodyne detection including speckle noise: Aircraft/shuttle measurements of O3, H2O, and NH3 with pulsed tunable CO2lasers

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    A parametric analysis of DIAL sensitivity with heterodyne detection is presented and comparisons with direct detection are discussed. Examples are given for monitoring vertical distributions of O3, H2O, and NH3 using a ground-, aircraft-, or shuttle-based pulsed tunable CO2 laser DIAL system. Results indicate that maximum sensitivity at minimum laser energy per measurement requires multiple pulse operation with the energy per pulse selected so that the measured photon rate is approximately equal to the detector IF bandwidth. Measurement sensitivities can be maximized and interference effects minimized by fine adjustment of measurement frequencies using the tunability of high pressure lasers. The use of rare isotope lasers minimizes loss due to CO2 atmospheric absorption

    DIAL with heterodyne detection including speckle noise: Aircraft/shuttle measurements of O3, H2O, and NH3 with pulsed tunable CO2 lasers

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    Atmospheric trace constituent measurements with higher vertical resolution than attainable with passive radiometers are discussed. Infrared differential absorption lidar (DIAL), which depends on Mie scattering from aerosols, has special advantages for tropospheric and lower stratospheric applications and has great potential importance for measurements from shuttle and aircraft. Differential absorption lidar data reduction involves comparing large amplitude signals which have small differences. The accuracy of the trace constituent concentration inferred from DIAL measurements depends strongly on the errors in determining the amplitude of the signals. Thus, the commonly used SNR expression (signal divided by noise in the absence of signal) is not adequate to describe DIAL measurement accuracy and must be replaced by an expression which includes the random coherent (speckle) noise within the signal. A comprehensive DIAL computer algorithm is modified to include heterodyne detection and speckle noise. Examples for monitoring vertical distributions of O3, H2O, and NH3 using a ground-, aircraft-, or shuttle-based pulsed tunable CO2 laser DIAL system are given

    Development of electromagnetic analysis methods for large aperture antennas

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    Both deterministic and statistical analysis methods for investigating large aperture antenna radiation patterns are examined. The effects of surface errors on radiation patterns are discussed

    Temperature dependence of the triplet diffusion and quenching rates in films of an Ir(ppy)(3)-cored dendrimer

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    We study photoluminescence and triplet-triplet exciton annihilation in a neat film of a fac-tris(2-phenylpyridyl)iridium(III) [Ir(ppy)(3)]-cored dendrimer and in its blend with a 4,4(')-bis(N-carbazolyl)biphenyl host for the temperature range of 77-300 K. The nearest neighbor hopping rate of triplet excitons is found to increase by a factor of 2 with temperature between 150 and 300 K and is temperature independent at lower temperature. The intermolecular quenching rate follows the Arrhenius law with an activation energy of 7 meV, which can be explained by stronger dipole-dipole interactions with the donor molecule in the higher triplet substate. The results indicate that energy disorder has no significant effect on triplet transport and quenching in these materials

    Triplet exciton diffusion and phosphorescence quenching in Iridium(III)-Centered dendrimers

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    A study of triplet-triplet exciton annihilation and nonradiative decay in films of iridium(III)-centered phosphorescent dendrimers is reported. The average separation of the chromophore was tuned by the molecular structure and also by blending with a host material. It was found that triplet exciton hopping is controlled by electron exchange interactions and can be over 600 times faster than phosphorescence quenching. Nonradiative decay occurs by weak dipole-dipole interactions and is independent of exciton diffusion, except in very thin films
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